Product ID:1,2-PHENYLENEDIAMINE, SUBLIMED, (SUPP DATA)
MSDS Date:11/04/1989
FSC:6810
NIIN:00N014556
MSDS Number: BKLBW

Info Phone: 414-273-3850

Cage: 60928

Telephone: 414-273-3850

Cage: 60928

O-PHENYLENEDIAMINE

CAS: 95-54-5

RTECS: SS7875000

Fraction By Weight: 99%+

ACGIH TLV: 0.1 MG/M3; A2; 9192

LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL
IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
CHRONIC: MAY CAUSE ALLERGIC SKIN REACTION. TARGET ORGANS: BLADDER
& LIVER.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES & SKIN: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND
SHOES. DISCARD CONTAMINATED CLOTHING AND SHOES. INHAL: REMOVE TO
FRESH AIR . IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD
IMMEDIATELY .

Extinguishing Media:WATER SPRAY. CO*2, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND PROTECTIVE
CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:EVAC AREA. WEAR NIOSH/MSHA APPROVED SCBA,
RUBBER BOOTS AND HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS AND
DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE
DISPOSAL. VENTILATE AR EA AND WASH SPILL SITE AFTER MATERIAL
PICKUP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE DUST. KEEP TIGHTLY
CLOSED. STORE IN A COOL DRY PLACE.
Other Precautions:AVOID ALL CONTACT. CARCINOGEN. IRRITANT. SENSITIZER.
HARMFUL SOLID.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
PART NO: ZONE-REFINED, 99+% 27578-6. LD50-LC50 MIX: LD50:(ORL,RAT) 1070
MG/KG, (IPR,RAT) 516 MG/KG, (UNR,RAT) 660 MG/KG, (IPR,MUS) 245
MG/KG, (SCU,MUS) 450 MG/KG, (UNR,MUS) 470 MG/KG, (UNR,GPG) 360 MG
/KG, (ORL,BWD) 133 MG/KG.

HCC:T4
Boiling Pt:B.P. Text:493F,256C
Melt/Freeze Pt:M.P/F.P Text:217F,103C
Vapor Pres:0.01 @ 25C
Vapor Density:3.7
Appearance and Odor:WHITE CRYSTALLINE POWDER.

STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:MAY DARKEN ON STORAGE.
Hazardous Decomposition Products:TOXIC FUMES OF: CO & CO*2. NO*X.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL
LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.